The following mass spectra of picolinyl ester derivatives of fatty
acids can be accessed directly from the tabulated
links below. No comments or interpretation are provided here, as the general principles
are discussed elsewhere. More spectra will be added from time to time as
they become available.
Picolinyl esters of saturated straight-chain fatty acids (including those
labelled with stable isotopes) |
| Fatty acid |
M+ |
Fatty acid |
M+ |
|
| acetate (2:0) |
151 |
octadecanoate (18:0) |
375 |
| butyrate (4:0) |
179 |
nonadecanoate (19:0) |
389 |
| hexanoate (6:0) |
207 |
eicosanoate (20:0) |
403 |
| octanoate (8:0) |
235 |
heneicosanoate (21:0) |
417 |
| decanoate (10:0) |
263 |
docosanoate (22:0) |
431 |
| undecanoate (11:0) |
277 |
tricosanoate (23:0) |
445 |
| dodecanoate (12:0) |
291 |
tetracosanoate (24:0) |
459 |
| tridecanoate (13:0) |
305 |
pentacosanoate (25:0) |
473 |
| tetradecanoate (14:0) |
319 |
hexacosanoate (26:0) |
487 |
| pentadecanoate (15:0) |
333 |
heptacosanoate (27:0) |
501 |
| hexadecanoate (16:0) |
347 |
octacosanoate (28:0) |
515 |
| heptadecanoate (17:0) |
361 |
triacontanoate (30:0) |
543 |
|
| 2,2D-hexadecanoate |
349 |
16,17D-octadecanoate |
377 |
| 3,3D-hexadecanoate |
349 |
17,18D-octadecanoate |
377 |
| 4,4D-hexadecanoate |
349 |
D35-octadecanoate |
410 |
| 9,10D-octadecanoate |
377 |
|
|
| 2-13C-hexadecanoate |
348 |
1-13C-octadecanoate |
376 |
Picolinyl esters of saturated branched-chain fatty acids |
| Fatty acid |
M+ |
Fatty acid |
M+ |
|
| 10-methyl-undecanoate (iso) |
291 |
13-methyl-eicosanoate |
417 |
| 10-methyl-dodecanoate (anteiso) |
305 |
14-methyl-eicosanoate |
417 |
| 11-methyl-dodecanoate (iso) |
305 |
17-methyl-eicosanoate |
417 |
| 12-methyl-tridecanoate (iso) |
319 |
18-methyl-eicosanoate (anteiso) |
417 |
| 3-methyl-tetradecanoate |
333 |
19-methyl-eicosanoate (iso) |
417 |
| 9-methyl-tetradecanoate |
333 |
18-methyl-heneicosanoate |
431 |
| 12-methyl-tetradecanoate (anteiso) |
333 |
19-methyl-heneicosanoate (anteiso) |
431 |
| 13-methyl-tetradecanoate (iso) |
333 |
20-methyl-heneicosanoate (iso) |
431 |
| 3-methyl-pentadecanoate |
347 |
15-methyl-docosanoate |
445 |
| 13-methyl-pentadecanoate (anteiso) |
347 |
20-methyl-docosanoate (anteiso) |
445 |
| 14-methyl-pentadecanoate (iso) |
347 |
21-methyl-docosanoate (iso) |
445 |
| 3-methyl-hexadecanoate |
361 |
15-methyl-tricosanoate |
459 |
| 10-methyl-hexadecanoate |
361 |
22-methyl-tricosanoate (iso) |
459 |
| 13-methyl-hexadecanoate |
361 |
17-methyl-tetracosanoate |
473 |
| 14-methyl-hexadecanoate (anteiso) |
361 |
18-methyl-tetracosanoate |
473 |
| 15-methyl-hexadecanoate (iso) |
361 |
22-methyl-tetracosanoate (anteiso) |
473 |
| 10-methyl-heptadecanoate |
375 |
23-methyl-tetracosanoate (iso) |
473 |
| 14-methyl-heptadecanoate |
375 |
24-methyl-pentacosanoate (iso) |
487 |
| 15-methyl-heptadecanoate (anteiso) |
375 |
20-methyl-hexacosanoate |
501 |
| 16-methyl-heptadecanoate (iso) |
375 |
21-methyl-hexacosanoate |
501 |
| 10-methyl-octadecanoate |
389 |
24-methyl-hexacosanoate (anteiso) |
501 |
| 11-methyl-octadecanoate |
389 |
25-methyl-hexacosanoate (iso) |
501 |
| 15-methyl-octadecanoate |
389 |
26-methyl-heptacosanoate (iso) |
515 |
| 16-methyl-octadecanoate (anteiso) |
389 |
22-methyl-octacosanoate |
529 |
| 17-methyl-octadecanoate (iso) |
389 |
26-methyl-octacosanoate (anteiso) |
529 |
| 10-methyl-nonadecanoate |
403 |
28-methyl-nonacosanoate (iso) |
543 |
| 16-methyl-nonadecanoate |
403 |
28-methyl-triacontanoate (anteiso) |
557 |
| 18-methyl-nonadecanoate (iso) |
403 |
30-methyl-dotriacontanoate (anteiso) |
585 |
|
| 3,7,11-trimethyl-dodecanoate |
333 |
2,6,10,14-tetramethyl-pentadecanoate |
389 |
| 4,8,12-trimethyl-tridecanoate |
347 |
8,10-dimethyl-hexadecanoate |
375 |
| 3,13-dimethyl-tetradecanoate |
347 |
3,7,11,15-tetramethyl-hexadecanoate |
403 |
| 5,9,13-trimethyl-tetradecanoate |
361 |
|
|
Picolinyl esters of monoenoic fatty acids (including branched-chain) |
| Fatty acid |
M+ |
Fatty acid |
M+ |
|
| 9-dodecenoate (9-12:1) |
289 |
7-nonadecenoate (7-19:1) |
387 |
| 4-tetradecenoate (4-14:1) |
317 |
8-nonadecenoate (8-19:1) |
387 |
| 7-tetradecenoate (7-14:1) |
317 |
9-nonadecenoate (9-19:1) |
387 |
| 9-tetradecenoate (9-14:1) |
317 |
11-nonadecenoate (11-19:1) |
387 |
| 5-pentadecenoate (5-15:1) |
331 |
12-nonadecenoate (12-19:1) |
387 |
| 9-pentadecenoate (9-15:1) |
331 |
5-eicosenoate (5-20:1) |
401 |
| 2-hexadecenoate (2-16:1) |
345 |
7-eicosenoate (7-20:1) |
401 |
| 3-hexadecenoate (3-16:1) |
345 |
9-eicosenoate (9-20:1) |
401 |
| 4-hexadecenoate (4-16:1) |
345 |
11-eicosenoate (11-20:1) |
401 |
| trans-6-hexadecenoate (6-16:1) |
345 |
13-eicosenoate (13-20:1) |
401 |
| 7-hexadecenoate (7-16:1) |
345 |
15-eicosenoate (15-20:1) |
401 |
| 9-hexadecenoate (9-16:1) |
345 |
7-heneicosenoate (7-21:1) |
415 |
| 10-hexadecenoate (10-16:1) |
345 |
13-heneicosenoate (13-21:1) |
415 |
| 11-hexadecenoate (11-16:1) |
345 |
|
|
| 8-heptadecenoate (8-17:1) |
359 |
5-docosenoate (5-22:1) |
429 |
| 9-heptadecenoate (9-17:1) |
359 |
7-docosenoate (7-22:1) |
429 |
| 11-heptadecenoate (11-17:1) |
359 |
11-docosenoate (11-22:1) |
429 |
|
|
13-docosenoate (13-22:1) |
429 |
| 2-octadecenoate (2-18:1) |
373 |
15-docosenoate (15-22:1) |
429 |
| 3-octadecenoate (3-18:1) |
373 |
|
|
| 4-octadecenoate (4-18:1) |
373 |
9-tetracosenoate (9-24:1) |
457 |
| 5-octadecenoate (5-18:1) |
373 |
15-tetracosenoate (15-24:1) |
457 |
| 6-octadecenoate (6-18:1) |
373 |
17-tetracosenoate (17-24:1) |
457 |
| 7-octadecenoate (7-18:1) |
373 |
9-pentacosenoate (9-25:1) |
471 |
| 8-octadecenoate (8-18:1) |
373 |
16-pentacosenoate (16-25:1) |
471 |
| 9-cis-octadecenoate (9c-18:1) |
373 |
18-pentacosenoate (18-25:1) |
471 |
| 9-trans-octadecenoate (9t-18:1) |
373 |
9-hexacosenoate (9-26:1) |
485 |
| 10-octadecenoate (10-18:1) |
373 |
17-hexacosenoate (17-26:1) |
485 |
| 11-octadecenoate (11-18:1) |
373 |
19-hexacosenoate (19-26:1) |
485 |
| 12-octadecenoate (12-18:1) |
373 |
19-octacosenoate (19-28:1) |
513 |
| 13-octadecenoate (13-18:1) |
373 |
21-octacosenoate (21-28:1) |
513 |
| 14-octadecenoate (14-18:1) |
373 |
21-triacontenoate (21-30:1) |
541 |
| 15-octadecenoate (15-18:1) |
373 |
23-triacontenoate (23-30:1) |
541 |
| 16-octadecenoate (16-18:1) |
373 |
23-dotriacontenoate (23-32:1) |
569 |
| 17-octadecenoate (17-18:1) |
373 |
25-dotriacontenoate (25-32:1) |
569 |
|
| 13-methyl-tetradec-4-enoate |
331 |
15-methyl-hexadec-9-enoate |
359 |
| 14-methyl-pentadec-6-enoate |
345 |
16-methyl-heptadec-9-enoate |
373 |
| 2-methylene-hexadecanoate |
359 |
17-methyl-octadec-8-enoate |
387 |
| 14-methyl-hexadec-6-enoate |
359 |
18-methyl-eicos-7-enoate |
415 |
| 15-methyl-hexadec-6-enoate |
359 |
|
|
Picolinyl esters of dienoic fatty acids (including branched-chain) |
| Fatty acid |
M+ |
Fatty acid |
M+ |
|
| 5,9-hexadecadienoate (5,9-16:2) |
343 |
9,12-nonadecadienoate (9,12-19:2) |
385 |
| 7,10-hexadecadienoate (16:2(n-6)) |
343 |
5,9-eicosadienoate (5,9-20:2) |
399 |
| 9,12-hexadecadienoate (9,12-16:2) |
343 |
5,11-eicosadienoate (5,11-20:2) |
399 |
| 5,9-heptadecadienoate (5,9-17:2) |
357 |
5,13-eicosadienoate (5,13-20:2) |
399 |
| 7,10-heptadecadienoate (7,10-17:2) |
357 |
7,13-eicosadienoate (7,13-20:2) |
399 |
| 9,12-heptadecadienoate (9,12-17:2) |
357 |
8,11-eicosadienoate (8,11-20:2) |
399 |
|
|
9,13-eicosadienoate (9,13-20:2) |
399 |
| 2,5-octadecadienoate (2,5-18:2) |
371 |
10,13-eicosadienoate (20:2(n-7)) |
399 |
| 3,6-octadecadienoate (3,6-18:2) |
371 |
11,14-eicosadienoate (20:2(n-6)) |
399 |
| 4,7-octadecadienoate (4,7-18:2) |
371 |
13,16-eicosadienoate (13,16-20:2) |
399 |
| 5,8-octadecadienoate (5,8-18:2) |
371 |
5,9-heneicosadienoate (5,9-21:2) |
413 |
| 6,9-octadecadienoate (6,9-18:2) |
371 |
5,9-docosadienoate (5,9-22:2) |
427 |
| 7,10-octadecadienoate (7,10-18:2) |
371 |
5,13-docosadienoate (5,13-22:2) |
427 |
| 8,11-octadecadienoate (8,11-18:2) |
371 |
7,13-docosadienoate (7,13-22:2) |
427 |
| 9,12-octadecadienoate (18:2 (n-6)) |
371 |
7,15-docosadienoate (7,15-22:2) |
427 |
| 10,13-octadecadienoate (10,13-18:2) |
371 |
13,16-docosadienoate (22:2(n-6)) |
427 |
| 11,14-octadecadienoate (11,14-18:2) |
371 |
5,9-tetracosadienoate (5,9-24:2) |
455 |
| 12,15-octadecadienoate (12,15-18:2) |
371 |
7,17-tetracosadienoate (7,17-24:2) |
455 |
| 13,16-octadecadienoate (13,16-18:2) |
371 |
15,18-tetracosadienoate (24:2(n-6)) |
455 |
| 14,17-octadecadienoate (14,17-18:2) |
371 |
5,9-pentacosadienoate (5,9-25:2) |
469 |
|
| 2,6-octadecadienoate (2,6-18:2) |
371 |
5,9-hexacosadienoate (5,9-26:2) |
483 |
| 3,5-octadecadienoate (3,5-18:2) |
371 |
9,19-hexacosadienoate (9,19-26:2) |
483 |
| 5,9-octadecadienoate (5,9-18:2) |
371 |
17,20-hexacosadienoate (26:2(n-6)) |
483 |
| 5,11-octadecadienoate (5,11-18:2) |
371 |
5,9-heptacosadienoate (5,9-27:2) |
497 |
| 5,12-octadecadienoate (5,12-18:2) |
371 |
5,9-octacosadienoate (5,9-28:2) |
511 |
| 6,10-octadecadienoate (6,10-18:2) |
371 |
17,21-octacosadienoate (17,21-28:2) |
511 |
| 6,11-octadecadienoate (6,11-18:2) |
371 |
|
|
| 6,12-octadecadienoate (6,12-18:2) |
371 |
19,23-triacontadienoate (19,23-30:2) |
539 |
| 7,11-octadecadienoate (7,11-18:2) |
371 |
|
|
| 7,12-octadecadienoate (7,12-18:2) |
371 |
21,25-dotriacontadienoate (21,25-32:2) |
567 |
| 8,12-octadecadienoate (8,12-18:2) |
371 |
|
|
| 9c,11t-octadecadienoate (9c,11t-18:2) |
371 |
|
|
| 10t,12c-octadecadienoate (10t,12c-18:2) |
371 |
|
|
|
| 23-methyl-tetracosa-5,9-dienoate |
469 |
25-methyl-hexacosa-5,9-dienoate |
497 |
| 24-methyl-pentacosa-5,9-dienoate |
483 |
22-methyl-octacosa-5,9-dienoate |
511 |
Picolinyl esters of trienoic fatty acids |
| Fatty acid |
M+ |
Fatty acid |
M+ |
|
| 4,7,10-hexadecatrienoate (16:3(n-6)) |
341 |
8,11,14-eicosatrienoate (20:3(n-6)) |
397 |
| 6,9,12-hexadecatrienoate (6,9,12-16:3) |
341 |
11,14,17-eicosatrienoate (20:3(n-3)) |
397 |
| 7,10,13-hexadecatrienoate (16:3(n-3)) |
341 |
7,13,16-docosatrienoate (7,13,16-22:3) |
425 |
| 6,9,12-heptadecatrienoate (6,9,12-17:3) |
355 |
5,9,17-tetracosatrienoate (5,9,17-24:3) |
453 |
| 8,11,14-heptadecatrienoate (17:3(n-3) |
355 |
|
|
| 3,9,12-octadecatrienoate (3,9,12-18:3) |
369 |
5,9,17-pentacosatrienoate (5,9,17-25:3) |
467 |
| 5,9,12-octadecatrienoate (5,9,12-18:3) |
369 |
5,9,19-pentacosatrienoate (5,9,19-25:3) |
467 |
| 6,9,12-octadecatrienoate (18:3(n-6)) |
369 |
5,9,17-hexacosatrienoate (5,9,17-26:3) |
481 |
| 9,12,15-octadecatrienoate (18:3(n-3)) |
369 |
5,9,19-hexacosatrienoate (5,9,19-26:3) |
481 |
|
|
5,9,19-heptacosatrienoate (5,9,19-27:3) |
495 |
| 6,10,12-octadecatrienoate (6,10,12-18:3) |
369 |
5,9,19-octacosatrienoate (5,9,19-28:3) |
509 |
| 9c,11t,13t-octadecatrienoate (9,11,13-18:3) |
369 |
5,9,21-octacosatrienoate (5,9,21-28:3) |
509 |
| 9t,11t,13t-octadecatrienoate (9,11,13-18:3) |
369 |
5,9,22-nonacosatrienoate (5,9,22-29:3) |
523 |
| 8,11,14-nonadecatrienoate (8,11,14-19:3) |
383 |
5,9,23-triacontatrienoate (5,9,23-30:3) |
537 |
| 5,8,11-eicosatrienoate (20:3(n-9)) |
397 |
5,9,25-dotriacontatrienoate (5,9,25-32:3) |
565 |
| 5,9,13-eicosatrienoate (5,9,13-20:3) |
397 |
5,9,25-tritriacontatrienoate (5,9,25-33:3) |
579 |
| 5,11,14-eicosatrienoate (5,11,14-20:3) |
397 |
5,9,27-tetratriacontatrienoate (5,9,27-34:3) |
593 |
| 7,11,14-eicosatrienoate (7,11,14-20:3) |
397 |
|
|
Picolinyl esters of tetra-, penta- and hexaenoic fatty acids |
| Fatty acid |
M+ |
Fatty acid |
M+ |
|
| 4,7,10,13-hexadecatetraenoate (16:4(n-3)) |
339 |
5,11,14,17-eicosatetraenoate (5,11,14,17-20:4) |
395 |
| 6,9,12,15-hexadecatetraenoate (16:4(n-1)) |
339 |
8,11,14,17-eicosatetraenoate (20:4(n-3)) |
395 |
| 5,9,12,15-octadecatetraenoate (5,9,12,15-18:4) |
367 |
7,10,13,16-docosatetraenoate (22:4(n-6)) |
423 |
| 6,9,12,15-octadecatetraenoate (18:4(n-3)) |
367 |
9,13,15,18-docosatetraenoate (24:4(n-6)) |
451 |
| 8,11,14,17-octadecatetraenoate (18:4(n-1)) |
367 |
5,9,19,23-triacontatetraenoate (5,9,19,23-30:4) |
535 |
| 5,8,11,14-nonadecatetraenoate (19:4(n-5)) |
381 |
5,9,21,25-dotriacontatetraenoate (5,9,21,25-32:4) |
563 |
| 5,8,11,14-eicosatetraenoate (20:4(n-6)) |
395 |
5,9,23,27-tetratriacontatetraenoate (5,9,23,27-34:4) |
591 |
|
| 2,6,9,12,15-octadecapentaenoate (2,6,9,12,15-18:5) |
365 |
4,7,10,13,16-docosapentaenoate (22:5(n-6)) |
421 |
| 3,6,9,12,15-octadecapentaenoate (18:5(n-3)) |
365 |
7,10,13,16,19-docosapentaenoate (22:5(n-3)) |
421 |
| 5,8,11,14,17-eicosapentaenoate (20:5(n-3)) |
393 |
9,12,15,18,21-tetracosapentaenoate (24:5(n-3)) |
449 |
| 6,9,12,15,18-heneicosapentaenoate (21:5(n-3)) |
407 |
|
|
|
| 4,7,10,13,16,19-docosahexaenoate (22:6(n-3)) |
419 |
6,9,12,15,18,21-tetracosahexaenoate (24:6(n-3)) |
447 |
Picolinyl esters of allenic and acetylenic fatty acids |
| Fatty acid |
M+ |
Fatty acid |
M+ |
|
| 4,5-tetradecadienoate (4,5-14:2) |
315 |
8,9-octadecadienoate (8,9-18:2) |
371 |
| 10,11-tetradecadienoate (10,11-14:2) |
315 |
9,10-octadecadienoate (9,10-18:2) |
371 |
| 11,12-tetradecadienoate (11,12-14:2) |
315 |
10,11-octadecadienoate (10,11-18:2) |
371 |
| 12,13-tetradecadienoate (12,13-14:2) |
315 |
11,12-octadecadienoate (11,12-18:2) |
371 |
| 5,6-octadecadienoate (5,6-18:2) |
371 |
12,13-octadecadienoate (12,13-18:2) |
371 |
| 6,7-octadecadienoate (6,7-18:2) |
371 |
13,14-octadecadienoate (13,14-18:2) |
371 |
| 7,8-octadecadienoate (7,8-18:2) |
371 |
|
|
|
| octadeca-9-ynoate |
371 |
6,8-octadecadiynoate |
367 |
|
|
7,9-octadecadiynoate |
367 |
| 5,7-nonadiynoate |
241 |
8,10-octadecadiynoate |
367 |
| 9,11-dodecadiynoate |
283 |
9,11-octadecadiynoate |
367 |
| 4,6-tetradecadiynoate |
311 |
10,12-octadecadiynoate |
367 |
| 5,7-hexadecadiynoate |
339 |
|
|
| 10,12-heptadecadiynoate |
353 |
octadeca-9-yn-trans-11-enoate |
369 |
| 12,16-heptadecadiynoate |
353 |
octadeca-9-en-12-ynoate |
369 |
|
|
octadeca-14-yn-17-enoate |
369 |
| 2,6-octadecadiynoate |
367 |
octadeca-6,9-dien-12-ynoate |
367 |
| 4,8-octadecadiynoate |
367 |
octadeca-8,10-dien-12-ynoate |
367 |
| 5,9-octadecadiynoate |
367 |
|
|
| 6,10-octadecadiynoate |
367 |
octadeca-6-yn-9,12,15-trienoate |
365 |
| 7,11-octadecadiynoate |
367 |
|
|
| 8,12-octadecadiynoate |
367 |
eicosa-11-en-14-ynoate |
397 |
| 9,13-octadecadiynoate |
367 |
eicosa-11-yn-trans-13-enoate |
397 |
| 10,14-octadecadiynoate |
367 |
docosa-13-yn-trans-15-enoate |
425 |
| 11,15-octadecadiynoate |
367 |
tetracosa-15-yn-trans-17-enoate |
453 |
| 12,16-octadecadiynoate |
367 |
hexacosa-17-yn-trans-19-enoate |
481 |
| 13,17-octadecadiynoate |
367 |
octacosa-19-yn-trans-21-enoate |
509 |
Picolinyl esters of natural cyclic fatty acids |
| Fatty acid |
M+ |
Fatty acid |
M+ |
|
| 9,10-methylene-hexadecanoate |
359 |
11,12-methylene-octadecanoate |
387 |
| 9,10-methylene-octadecanoate |
387 |
11,12-methylene-eicosanoate |
415 |
|
| 8,9-methylene-heptadec-9-enoate |
371 |
9,10-methylene-octadec-9-enoate |
385 |
|
| 3-cyclopentylpropanoate |
233 |
11-cyclopentylundecanoate |
345 |
| 3-cyclopent-2-enylpropanoate |
231 |
11-cyclopent-2-enylundecanoate |
343 |
| 4-cyclopentylbutyrate |
247 |
13-cyclopentyltridecanoate |
373 |
| 4-cyclopent-2-enylbutyrate |
245 |
13-cyclopent-2-enyltridecanoate |
371 |
| 5-cyclopentylpentanoate |
261 |
13-cyclopent-2-enyltridec-4-enoate |
369 |
| 5-cyclopent-2-enylpentanoate |
259 |
13-cyclopent-2-enyltridec-6-enoate |
369 |
| 6-cyclopentylhexanoate |
275 |
15-cyclopentylpentadecanoate |
401 |
| 6-cyclopent-2-enylhexanoate |
273 |
15-cyclopent-2-enylpentadecanoate |
399 |
| 7-cyclopent-2-enylheptanoate |
287 |
15-cyclopent-2-enylpentadec-9-enoate |
397 |
| 9-cyclopent-2-enylnonanoate |
315 |
|
|
| 11-phenyl-undecanoate |
353 |
13-phenyl-tridecanoate |
381 |
| 13-phenyl-tridec-9-enoate |
379 |
15-phenyl-pentadec-9-enoate |
407 |
Picolinyl esters of epoxy, keto and hydroxy fatty acids |
| Fatty acid |
M+ |
Fatty acid |
M+ |
|
| 9,10-epoxyoctadecanoate |
389 |
12,13-epoxyoctadec-9-enoate |
387 |
|
| 8-(5-hexyl-2-furyl)-octanoate |
385 |
|
|
|
| 15-ethoxypentadecanoate |
377 |
17-ethoxyheptadec-9-enoate |
403 |
| 15-ethoxypentadec-10-enoate |
375 |
19-ethoxynonadec-9-enoate |
431 |
| 10-methyl,17-ethoxyheptadecanoate |
419 |
|
|
| 9-methoxydecanoate |
293 |
15-methoxyhexadecanoate |
377 |
| 11-methoxydodecanoate |
321 |
17-methoxyoctadec-9-enoate |
403 |
| 13-methoxytetradecanoate |
349 |
|
|
|
| 4-oxo-dodecanoate |
305 |
11-oxo-nonadecanoate |
403 |
| 9-oxo-tetradecanoate |
333 |
15-oxo-eicosanoate |
417 |
| 8-oxo-hexadecanoate |
361 |
|
|
| 14-oxo-hexadecanoate |
361 |
9-oxo-tetradec-5-enoate |
331 |
|
|
8-oxo-hexadec-11-enoate |
359 |
| 5-oxo-octadecanoate |
389 |
8-oxo-hexadec-12-enoate |
359 |
| 7-oxo-octadecanoate |
389 |
8-oxo-hexadec-13-enoate |
359 |
| 10-oxo-octadecanoate |
389 |
11-oxo-hexadec-7-enoate |
359 |
| 10-oxo-14,15-deutero-octadecanoate |
391 |
10-oxo-octadec-13-enoate |
387 |
| 12-oxo-octadecanoate |
389 |
10-oxo-octadec-14-enoate |
387 |
| 12-oxo-9,10-deutero-octadecanoate |
391 |
10-oxo-octadec-15-enoate |
387 |
| 13-oxo-octadecanoate |
389 |
12-oxo-octadec-5-enoate |
387 |
| 13-oxo-9,10-deutero-octadecanoate |
391 |
12-oxo-octadec-9-enoate |
387 |
| 16-oxo-octadecanoate |
389 |
13-oxo-octadec-9-enoate |
387 |
| 16-oxo-9,10-deutero-octadecanoate |
391 |
16-oxo-octadec-9-enoate |
387 |
| 17-oxo-9,10-deutero-octadecanoate |
391 |
17-oxo-octadec-9-enoate |
387 |
|
|
|
|
|
| 5-oxo-octadecanoate - oxime |
418 |
12-oxo-octadecanoate - oxime |
418 |
| 7-oxo-octadecanoate - oxime |
418 |
|
|
|
| 2-hydroxyhexadecanoate |
363 |
|
|
| 2-hydroxyoctadecanoate |
391 |
12-hydroxyoctadecanoate |
391 |
|
| 12-hydroxyoctadec-9-enoate |
389 |
12-hydroxyoctadec-9-enoate - TMS ether |
461 |
| 15-hydroxyoctadec-9,12-dienoate |
387 |
|
|
Picolinyl esters of dicarboxylic fatty acids |
| Fatty acid |
M+ |
Fatty acid |
M+ |
|
| 1,6-hexanedioate |
328 |
1,11-undecanedioate |
398 |
| 1,9-nonanedioate |
370 |
|
|
Picolinyl esters of halogenated fatty acids |
| Fatty acid |
M+ |
Fatty acid |
M+ |
|
| 16-fluoro-hexadecanoate |
365 |
18-fluoro-octadec-9,12-dienoate |
389 |
| 16-fluoro-hexadec-7-enoate |
363 |
20-fluoro-eicosanoate |
421 |
| 16-fluoro-hexadec-9-enoate |
363 |
20-fluoro-eicos-9-enoate |
419 |
| 18-fluoro-octadecanoate |
393 |
20-fluoro-eicos-11-enoate |
419 |
| 18-fluoro-octadec-9-enoate |
391 |
|
|
|
| 12,12,12-trifluoro-dodecanoate |
345 |
6,6-difluoro-octadecanoate |
411 |
| 2-fluoro-hexadecanoate |
365 |
10,10-difluoro-octadecanoate |
411 |
| 2-fluoro-octadecanoate |
393 |
18,18,18-trifluoro-octadecanoate |
429 |
| 2,2-difluoro-octadecanoate |
411 |
|
|
|
| 14-chloro-tetradecanoate |
353 |
16-chloro-hexadec-9-enoate |
379 |
| 15-chloro-pentadecanoate |
367 |
18-chloro-octadec-9-enoate |
407 |
| 16-chloro-hexadecanoate |
381 |
|
|
|
| 2-bromo-hexadecanoate |
427 |
|
|
Picolinyl esters of thia fatty acids |
| Fatty acid |
M+ |
Fatty acid |
M+ |
|
| 2-thia-laurate |
309 |
7-thia-laurate |
309 |
| 3-thia-laurate |
309 |
8-thia-laurate |
309 |
| 4-thia-laurate |
309 |
9-thia-laurate |
309 |
| 5-thia-laurate |
309 |
10-thia-laurate |
309 |
| 6-thia-laurate |
309 |
11-thia-laurate |
309 |
|
| 2-thia-stearate |
393 |
10-thia-stearate |
393 |
| 3-thia-stearate |
393 |
11-thia-stearate |
393 |
| 4-thia-stearate |
393 |
12-thia-stearate |
393 |
| 5-thia-stearate |
393 |
13-thia-stearate |
393 |
| 6-thia-stearate |
393 |
14-thia-stearate |
393 |
| 7-thia-stearate |
393 |
15-thia-stearate |
393 |
| 8-thia-stearate |
393 |
16-thia-stearate |
393 |
| 9-thia-stearate |
393 |
17-thia-stearate |
393 |
|
| 6,7-dithia-stearate |
411 |
10,15-dithia-stearate |
411 |
| 6,8-dithia-stearate |
411 |
11,15-dithia-stearate |
411 |
| 6,9-dithia-stearate |
411 |
12,15-dithia-stearate |
411 |
| 6,10-dithia-stearate |
411 |
13,15-dithia-stearate |
411 |
| 6,11-dithia-stearate |
411 |
14,15-dithia-stearate |
411 |
